Pop superstar Katy Perry and country's darling and Grammy winner Kacey Musgraves are joining forces for 'CMT Crossroads,' and their episode will premiere on June 13 on CMT.

The two singers will share songs and stories, featuring exclusive collaborations of their hits. Included in the mix will be Perry's hits 'Roar' and 'Teenage Dream' and Musgraves' 'Follow Your Arrow' and 'Merry Go 'Round.'

Perry and Musgraves' episode marks the 50th episode of the network's longest-running music series, making it an especially exciting venture, as both women are stars in their field. In addition to airing on CMT, the episode, for the first time ever, will air on  VH1, MTV, MTV Hits and Palladia.

The episode will be a sneak peek into what fans may see on Perry's Prismatic Tour, when Musgraves will join her in August.

“I’ve been such a huge fan of Katy and her vision since I found out about her,” Musgraves says. ”And since she’s found out about me she’s been an amazing light and friend to me … In some ways we’re on opposite ends of the spectrum, but in a lot of ways our music makes total sense together. Her songs, while having grit, are so fun and it’ll be a cool challenge to throw a little country on ‘em.”

'CMT Crossroads' always makes great collaborations happen, showing that top-quality music knows no boundaries, and country music can create some pretty exciting partnerships. Recently, Dierks Bentley teamed up with OneRepublic and Lady Antebellum took the stage with Stevie Nicks.